Aliphatic polyisocyanate resin, hexamethylene diisocyanate monomer 0. Oxyester ephs 2272 is a linear polyester diol, developed primarily for the use in aliphatic pur technology, especially as a vocreducing copolyol in 2k pur high solid coatings. In volume terms, this family accounts for over half of all urethane coatings sold in the world. Aliphatic polyisocyanate resin, hexamethylene diisocyanate, and isophorone diisocyanate resin. Vulkem 350nf351nf table of contents vulkem 351nf gray part a msds 1 vulkem 351nf part b msds 7. Material safety data sheet carolinas auto supply house inc. Safety data sheets provide information about important health and safety topics, including. Our comprehensive range of desmodur polyisocyanates for flexible. Basonat hi series offers excellent gloss retention and light stability with outstanding weather, chemical, and abrasion resistance. Aliphatic polyisocyanate resin overexposure may cause asthmalike reactions with shortness of breath, wheezing, cough, which may be permanent. Aliphatic polyisocyanate resin polymer 15 40 72259735 nbutyl acetate 5 10 123864 light aromatic solvent naphtha 3 7 64742956 1,2,4trimethylbenzene 1 5 95636. Percent oshapel acgihtlv note unsaturated polyester base resin see index 55.
Workers involved in auto body repair, and refinishing can potentially be exposed to a wide range of air cont aminants. Along with covestro polyols, they are a key component for the production of exceptional polyurethanebased products with wideranging properties. Panel prepared this guidance to provide information about important health and safety considerations when working with aliphatic diisocyanates adis. An aliphatic polyisocyanate prepolymer obtained by reacting an aliphatic isocyanurate groupcontaining polyisocyanate with a shortchain diol, having a urethane bond content of 3. Polyisocyanate resin 9057914 10 30 parachlorobenzotrifluoride pcbtf 98566 7 quartz silicacrystalline 14808607 1 5 acetone 67641 1 5 fumed silica 112945525 1 5. Select positive pressure supplied air respirator tc19c or equivalent for isocyanates. Twocomponent systems consist of a polyisocyanate and a polyol that are mixed just prior to application and cure at room temperature. Material safety data sheet durathane white 30 eacs low voc version 1 print date 05092006 revision date. Material safety data sheet kresin copolymers february 15, 2002. Page 1 of 10 safety data sheet toluene diisocyanate. May cause eye irritation with discomfort, tearing, or blurred vision.
Material safety data sheet rcp50 2k hs speed primer sealer grey. Basonat hardeners are used in combination with binders containing hydroxyl groups for crosslinkers in twocomponent pur coatings. Sds safety data sheet resene uracryl 400 series hardener. Introduction of products polyisocyanate hardener tdihdi polyisocyanate tdihdi polyisocyanate this is hardener with the advantage of aromatic and aliphatic isocyanate. Generally, they are considered to be specialty materials used in significantly smaller quantities than the aromatic diisocyanates. Aliphatic isocyanates are used in the manufacture of light stable polyurethane and polyurea systems. The efficiency of the ventilation system must be monitored. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. The california department of public health has produced a fact sheet and new web pageexternal icon to provide information on health hazards from isocyanates. P501 dispose of contentscontainer in accordance with national regulations. The top countries of suppliers are china, taiwan, china, and south korea, from which the percentage of polyisocyanate resin supply is 74%, 22%, and 3% respectively. Msds 4 centari r acrylic enamel tints and miscellaneous factory packaged colors dupont performance coatings material safety data sheet april 1, 2011 page. When it comes to highquality polyurethane applications, desmodur polyisocyanates from covestro are renowned for their versatility.
Material safety data sheet vulkem 351 nf gray 5 gal ss h. An organic compound with two isocyanate groups is known as a diisocyanate. The top countries of suppliers are china, india, and south korea, from which the percentage of isocyanate hardener supply is 94%, 2%, and 1% respectively. Material safety data sheet date prepared 2011 hazard rating health 2 section i identification 0 least flammability 2 identity as used on label armor top hardener 1 slight 2 moderate reactivity 1 common name aliphatic polyisocyanate resin solution 3 high 4 extreme personal protection g section ii product components cas. Dow has a fundamental concern for all who make, distribute, and use its products, and for the environment in which we live. Used as a hardener or reactive diluent for 100% solids, solventborne and aqueous, twopack polyurethane coatings. Use adequate ventilation to keep airborne isocyanate levels below the exposure limits. Basonat polyisocyanates are aliphatic crosslinkers for highperformance coatings systems. Aliphatic polyisocyanate prepolymers and polyurethane resin. Material safety data sheet date prepared 2011 hazard rating health 2 section i identification 0 least flammability 2 identity as used on label armor top hardener 1 slight 2 moderate reactivity 1 common name aliphatic polyisocyanate resin solution 3 high.
Enamel, chromate, corlar r, variprime r and sealers axalta coating systems material safety data sheet january 1, 2015 page. Mar 20, 2019 hazards of isocyanates tdi, mdi, hdi in resins, coatings and paints. Product safety assessment mdibased isocyanate products. Polyisocyanate resin section iia product ingredient no. Liquid isocyanates and high isocyanate vapour concentrations will penetrate seals on self contained breathing apparatus scba should be used. It is applied to autimobile repair and general industry.
Us9376404b2 pentamethylene diisocyanate, method for. When heated above the defined flash points, these solvents emit flammable vapors, which when mixed with air, can burn or be explosive when exposed to any ignition source. Us3409579a us635382a us63538267a us3409579a us 3409579 a us3409579 a us 3409579a us 635382 a us635382 a us 635382a us 63538267 a us63538267 a us 63538267a us 3409579 a us3409579 a us 3409579a authority us united states prior art keywords resin polyisocyanate foundry binder phenol prior art date 19660801 legal status the legal status is an assumption and is not a. The information contained in this msds is based on data from sources. Isocyanate free polyurethane coatings for industrial metal. Msds a1481 part a 2 hexamethylene diisocyanate hdi 822060 osha not established acgih. Aliphatic polyisocyanate for lightfast and weatherresistant twopack polyurethane coatings. These polymers are used to make foam padding for mattresses and seat cushions. Organic compounds that contain an isocyanate group are referred to as isocyanates. Aliphatic isocyanates polyurethane and polyurea click. Safety data sheet polyurethane resin ur5634, part a. B component for water glass polyisocyanate based twocom ponent synthetic resin. Hybrid resins from polyisocyanate, epoxy resin and water glass.
The term adi polyisocyanates is used to address partially polymerized products from adi monomers. This hardener is aliphatic isocyanate based polyisocyanates. The information in this safety data sheet sds is believed to be correct as of. This concern is the basis for our product stewardship philosophy by. Click for samples or quote of aliphatic isocyanates for your polyurethane and polyurea formulations. Read all other component material safety data sheets. Hazards of isocyanates tdi, mdi, hdi in resins, coatings. Msds 4 r acrylic enamel tints and miscellaneous factory. Repeated exposure may cause allergic skin rash, itching, swelling. The following medical conditions may be aggravated by exposure. Repeated inhalation of vapor or aerosol at levels above the. If skin is exposed to an aliphatic polyisocyanate, wash it off thoroughly with large amounts of water and then. Ep1914255a2 aliphatic polyisocyanate prepolymers and.
Catalyzed polyol resin blend of proprietary composition, with surfactant. Polymeric hexamethylene diisocyanate in organic solvents. Diisocyanates are manufactured for the production of polyurethanes, a class of polymers. Guidance for working with march 201648148r 1r1 aliphatic. A wide variety of isocyanate hardener options are available to you, there are 177 suppliers who sells isocyanate hardener on, mainly located in asia. Safety data sheet toluene diisocyanate the chemical company. Hypersensitivity to product, allergies, and skin or. Aliphatic polyisocyanate resin polymer 15 40 72259735 nbutyl acetate 5 10 123864. This paper provides additional information to what is contained in your suppliers safety. Aliphatic diisocyanates adi are specialty intermediate chemicals used primarily to make durable coatings, adhesives, sealants, elastomers, and textiles, among other products. Safety data sheets epoxy and polyurethane casting systems. Material safety data sheet rcc22 41 30 minute ultraspeed clearcoat rch 2275 ultracure clearcoat activator normal. Chronic overexposure to isocyanate has also been reported to cause lung. Msds a1481 part a 1 material safety data sheet a1481 part a date of preparation.
Triiso distributes a range of low viscosity aliphatic isocyanates. Chemical product and company identification product code. Acrylic resin notavail none a none, o none additive notavail none a none, o none aliphatic polyisocyanate resin 28182812 none s 0. Aliphatic isocyanates polyurethane and polyurea click for.
Blocked isocyanate an overview sciencedirect topics. Carolina auto supply house urges each customer or recipient of this msds to study it carefully to become aware of and understand the hazards associated with. A pentamethylene diisocyanate is obtained by phosgenating pentamethylenediamine or its salt obtained by a biochemical method, and contains 5 to 400 ppm of a compound represented by the general formula 1 below and a compound represented by the general formula 2 below in total. Chemistry, structure and properties article in journal of materials science 457. Safety data sheets sds and labels should be checked to determine if products used at the. Absorb with inert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recover using pumps. Makrolon ag was the highperformance choice for the panoramic roof of bugattis veyron.
Painting involves matching paint colors, mixing paint formulations, and painting the repaired area using custom and conventional painting techniques. Among others, the range comprises products with very low viscosity and. The information contained in this msds is based on data from sources considered to be reliable but carolina auto supply house does not guarantee the accuracy or completeness thereof. Composite matrix resin cmr msds un1866 the information herein is given in good faith, but no warranty, express or implied, is made.
Blocked isocyanates are reaction products of isocyanates with, for example, phenols, oximes, caprolactam or. Sds, formerly known as material safety data sheets msds. The terms of this safety data sheet sds do not create or infer any warranty. Refer to other sections of this msds to determine the toxicity and. Safety data sheets epoxy and polyurethane casting systems sika.
In case of exposure to a high concentration of vapor or mist, remove person to fresh air. Get medical attention if irritation develops or persists. This effect may be delayed for several hours after exposure. This product is a liquid acrylic based resin with an acrylat characteristic odor. The inhalation of high vapor concentration may cause a headache and nausea. Storage keep container dry and tightly closed in a cool and well ventilated place. Material safety data sheet tremseal d 30cs version 2. A wide variety of polyisocyanate resin options are available to you, there are 58 suppliers who sells polyisocyanate resin on, mainly located in asia.
Polyurethanes are polymers that are formed by reacting an isocyanate, like toluenediisocyanate, methylene bisphenyl isocyanate or hexamethylene di isocyanate also referred to as hdi and alcohol. The american chemistry councils aliphatic diisocyanates. The information contained herein is based on the data available to us and is believed to be correct. Hazards of isocyanates tdi, mdi, hdi in resins, coatings and paints. Pubased lamination adhesives support the key trends shaping the flexible packaging market today and in the future. Generally, they are considered to be specialty materials used in significantly smaller quantities than. Eye contact in case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
This product is designed to be premixed with the polyisocyanate component or to be added just before application of two component systems. Show this safety data sheet to the medical personnel. Hybrid resins from polyisocyanate, epoxy resin and water. Msds safety data sheet sds for details on product hazards, recommended handling precautions and product storage. Isocyanate is the functional group with the formula r. Guide for handling isocyanates safe work australia.